|
|
S-adenosyl-L-methionine + dTDP-4-dehydro-2,6-dideoxy-alpha-D-glucose <=> S-adenosyl-L-homocysteine + dTDP-4-dehydro-3-C-methyl-2,6-dideoxy-alpha-D-glucose + H+
|
2.1.1
|
–
|
|
MetaCyc:
RXN-12931
|
|
|
|
dTDP-glucose <=> H2O + dTDP-4-dehydro-6-deoxy-D-glucose
|
4.2.1.46
dTDP-glucose 4,6-dehydratase
4.2.1.76
UDP-glucose 4,6-dehydratase
|
–
–
|
|
BRENDA:
BR425
KEGG:
R06513
MetaCyc:
DTDPGLUCDEHYDRAT-RXN
SABIO-RK:
2648;
8948
|
|
|
|
dTDP-4-dehydro-2,6-dideoxy-alpha-D-glucose + NADP+ <=> dTDP-3,4-didehydro-2,6-dideoxy-alpha-D-glucose + NADPH + H+
|
1.1.1.384
dTDP-3,4-didehydro-2,6-dideoxy-alpha-D-glucose 3-reductase
|
–
|
|
BRENDA:
BR51206
KEGG:
R05526
MetaCyc:
RXN-16262
|
|
|
|
dTDP-D-mycarose + NADP+ <=> dTDP-4-dehydro-3-C-methyl-2,6-dideoxy-alpha-D-glucose + NADPH + H+
|
1.1.1
|
–
|
|
MetaCyc:
RXN-12932
|
|
|
|
dTDP-4-dehydro-6-deoxy-D-glucose <=> dTDP-(2R,6S)-2,4-dihydroxy-6-methyl-2,6-dihydropyran-3-one + H2O + H+
|
4.2.1.159
dTDP-4-dehydro-6-deoxy-alpha-D-glucopyranose 2,3-dehydratase
|
–
|
|
BRENDA:
BR51536
KEGG:
R06428
MetaCyc:
RXN-12404
|
|
|
|
dTDP-D-boivinose + NADP+ <=> dTDP-4-dehydro-2,6-dideoxy-alpha-D-glucose + NADPH + H+
|
1.1.1
|
–
|
|
MetaCyc:
RXN-12921
|
|
|
|
dTTP + alpha-D-glucose_1-phosphate + H+ <=> dTDP-glucose + diphosphate
|
2.7.7.24
glucose-1-phosphate thymidylyltransferase
2.7.7.64
UTP-monosaccharide-1-phosphate uridylyltransferase
2.7.7.9
UTP---glucose-1-phosphate uridylyltransferase
|
–
–
–
|
|
BRENDA:
BR47871;
BS426212
KEGG:
R02328
MetaCyc:
DTDPGLUCOSEPP-RXN
SABIO-RK:
2281;
8935
|
|
|
|
dTDP-D-oliose + NADP+ <=> dTDP-4-dehydro-2,6-dideoxy-alpha-D-glucose + NADPH + H+
|
1.1.1
|
–
|
|
MetaCyc:
RXN-12930
|
|
|
|
dTDP-(2R,6S)-2,4-dihydroxy-6-methyl-2,6-dihydropyran-3-one + H+ <=> dTDP-3,4-didehydro-2,6-dideoxy-alpha-D-glucose
|
4.2.1.159
dTDP-4-dehydro-6-deoxy-alpha-D-glucopyranose 2,3-dehydratase
|
–
|
|
BRENDA:
BR51537
KEGG:
R11034
MetaCyc:
RXN-12943
|
|